Archive

Posts Tagged ‘See-Cure’

What adhesive should I use to bond a polyurethane tube to an ABS adapter?

April 20th, 2011
 Author: Nadine Blaesing
 

“Can you recommend the most appropriate UV-curable adhesive to bond ABS connectors to polyurethane tubing in a medical device application? It is a polyether aromatic polyurethane tube to a transparent ABS connector.”

 

For this type of application I suggest trying DYMAX 1161-M. This adhesive cures with UV and visible light and exhibits good adhesion to ABS and PUR. It also fluoresces blue for quality purposes. If you are interested in See-Cure patented color-change technology, I would recommend DYMAX See-Cure 1201-M-SC. This product is blue and helps verify that enough adhesive has been dispensed. Upon exposure to UV/visible light, the adhesive turns clear to confirm complete cure.

Add This! del.icio.us Digg Facebook reddit StumbleUpon

Adhesives, Medical , , , , , , ,

What adhesives can I use to bond Polyurethane?

April 8th, 2011
 Author: Nadine Blaesing
 

“We want to bond Polyurethane to PU, Polyurethane to latex, and PU to polycarbonate. A little flexibility would be helpful. Visibility of the bond would also be desirable. Do you have a product that meets these requirements?”

 

DYMAX offers 204-CTH-F light-curable adhesive, which is recommended for single-use medical devices made of Polyurethane, PVC, Polycarbonate, and many other plastics. This adhesive fluoresces blue under black light for quality purposes and is suitable for assembling rigid and flexible components due to its flexibility.

Since latex is very difficult to adhere to, 204-CTH-F may not provide the desired bond strength. Typically, a cyanoacrylate like DYMAX 222 Series is used for latex; however, it will not provide a flexible bond.

If you want to be able to see the adhesive while you dispense it and get confirmation of cure, I would suggest trying DYMAX 1201-M-SC or 211-CTH-SC. Both are light-curable adhesives equipped with DYMAX patented See-Cure color change technology. Adhesives formulated with See-Cure technology are visible when dispensed onto substrates due to their bright blue color while in the uncured stage. When fully cured, they become colorless to visually assure they have been cured.

Add This! del.icio.us Digg Facebook reddit StumbleUpon

Adhesives, Cyanoacrylates , , , , , ,

Determine When Full Adhesive Cure is Accomplished &
Create a Robust Light Curing Process

November 20th, 2009
 Author: Kyle Rhodes
 

"I am trying to understand the UV-curing process. How can I determine when an adhesive is fully cured? What are the critical parameters that I need to control in order to gain good consistency for the curing? Also, I was trying to cure some adhesive on a piece of stainless steel coupon. One small drop of adhesive was placed onto the coupon and formed a kind of round shaped droplet. I am wondering if the curing is more efficient on the surface of the droplet or on the inside of the droplet. Thanks a lot for your help!"

 

Very good question! Light-curable adhesives (whether it is by UV light, visible light, or a combination of UV and visible light) cure from the surface closest to the lamp, and then cure to depth. If you have a droplet, the surface will cure first, and then the rest of the dome will follow. The last area to cure would be against the substrate, so this leads us to the question:

 

How do you know when the adhesive is fully cured?

  • Adhesion to the substrate is one way to evaluate the full cure
  • A simple test is to try and use a tool to get underneath the droplet. If there is liquid at the interface, then it is not fully cured. You would need to increase either the intensity of the lamp, or increase the amount of time of exposure.
  • Most applications have a minimum energy needed to achieve good cure. The energy, or Joules/cm^2, is a multiplication of the intensity (Watts/cm^2) x dose (seconds). You want to build a process around the total amount of Joules needed to reach full cure, so you can vary either the intensity or time needed to cure, and as long as you reach the minimum energy for a given lamp, then you should have a robust process.

The best way to determine if you have a robust process would be to:

  • Run adhesion strength tests (bond laps or components together to see when full or maximum strength is achieved) or physical characterization (i.e. durometer, elongation, tensile, or modulus) at different conditions. When full strength is reached, additional energy (intensity or time) does not lead to an increase in properties.
  • Compare the results in your process to the manufacturers data sheet. The manufacturers data sheet may indicate that the material will ultimately reach a specific durometer (i.e. A-40, D-60, D-90). Under most conditions, if you were plotting durometer/hardness for example, the hardness will build (incomplete cure) and then plateau (complete cure).
  • Build in enough time to add a safety margin

It is important to have a radiometer as this device will tell you the intensity in Watts/cm^2 or mW/cm^2, which will be critical in the application.

 

The ability to cure on the surface can be affected by a phenomenon called oxygen inhibition. Some older adhesive technologies may be affected by oxygen during the cure process, which leaves a slightly tacky residue on the surface. The best way to overcome this issue is to start with a higher intensity, which would allow you to cure for a shorter time. New materials are being designed to overcome this issue, but lamp selection and bulb spectrum are important when developing a new process.

 

DYMAX has a new technology to help you define the parameters of a robust process, and ensure that during production the material is fully cured. See-Cure Technology is a patent-pending adhesive technology available in many DYMAX products that allows the adhesive to appear bright blue in the uncured state. Upon reaching full cure under a light source, the blue color will disappear, leaving a colorless clear adhesive in the bond line. It will only go clear when it has reached enough energy to be fully cured. This adhesive color-changing technology was designed to incorporate a safety margin before the color change happens, so is a great way to not only build a process, but have a quality inspection system within the adhesive to tell you if you have reached full cure.

 
Add This! del.icio.us Digg Facebook reddit StumbleUpon

Adhesives, Coatings, Curing Equipment , , , , , , , , , , , , , , , , , , , ,

Bonding PEBA and Polyethylene

July 23rd, 2009
 Author: Kyle Rhodes
 

“I need to bond PE to both metal and Pebax®. If possible, a light-cure product is preferable. Would the surface treatment be the same for PEBAX to PE? Do both materials need to be treated?”

 

There are a few light-curable adhesives that come to mind that will bond to both metals and plastics, and have good adhesion to both PEBA and PE. Treatment of the PE is a good idea, and methods include corona treatment of the PE, or plasma treatment with an oxygen-gas attachment. Regarding adhesion to PEBA, (as a block copolymer) this material can have different levels of a nylon characteristic. Usually, the higher the durometer, the more like nylon it will behave, which is a little more difficult to bond to. A lower durometer PEBA is typically easier to stick to. If you are bonding PEBA to PE, you would generally only need to treat the PE. If you are using a high durometer PEBA it would be a wise test to treat the PEBA and see if better bond results are found.

 

If you are looking for a recommendation from DYMAX, I suggest evaluating either 1161-M or 1168-M. Other competitive companies offer some very good adhesives for these substrates, and I am sure their technical support groups can help make a proper recommendation. There is a new technology available which can actually let you see the blue colored adhesive as it is dispensed, and upon cure will become clear. The See-Cure technology, as found in a product like 1202-M-SC, can bond to metal, PEBA, and PE (with treatment), as well as provide a safety feature by allowing the operator to see where the adhesive is dispensed, and when it has reached full cure.

Add This! del.icio.us Digg Facebook reddit StumbleUpon

Adhesives, Medical ,

Q&A’s: How to Save on Assembly Bonding Processes…

March 17th, 2009
 Author: Kyle Rhodes

 

DYMAX recently had a webinar informing people how to save 30% on their assembly bonding process. We talked about real-life ways to optimize assembly processes with cure-on-demand UV/Visible light-curable adhesives. This archived webinar is now available for viewing.

A lot of questions were asked during the webinar session. I decided to post a few below. Some of you may have the same questions in mind.

 

Question Answer
Can UV lights be added onto an XYZ robotic arm? Are they compatible with the software systems? Light sources can be mounted and used with many XYZ systems and integrated seamlessly into the software controls. Some systems offer the ability to dispense a bead or gasket and then follow the bead or gasket with the end of a lightguide from a high-intensity spot lamp system.
What thicknesses can the light-curable materials be used to? Typically, applications with a thickness of <0.25 inches are common. Best bond line thicknesses are usually 0.002-0.006 inches (0.05-0.15 mm), conformal coatings are typically 0.001-0.003 inches, and some special deep-section potting can be over 0.25 inches.
How heat resistant are the light-cure materials? This varies by product, but most will be in the 200-400°F temperature range.
Most processes are validated/established processes. How much costs have you seen associated with an initial implementation of a UV-curing system? This depends on the lamp type and application. Some starter R&D and low-production lamps start in the $2,500 range while other lamps with conveyors or XYZ tables can be much more. DYMAX offers a Trial Rental/Lease lamp program with 2 weeks free for trials and evaluations.
Can you explain See-Cure technology again? What are other methods to check cure quality?  See-Cure Technology utilizes a dye that loses its color with the light energy (intensity and time exposure). The color goes from blue to clear upon cure. Once the material is clear, it will remain clear, and be aesthetically pleasing to the eye. Other methods to check the state of cure is by either mechanical testing (such as tensile strength, durometer, and pull to destruction), or by chemical analytical testing (such as gas chromatograph on an extract sample, or FTIR of the cured material)
You mentioned “potting”. Can you please expand on? What is the maximum depth of the potting? Can you cover moisture cure technology? Potting is typically filling a small well or dam with adhesive to protect components, circuits, or seal a housing/port. The viscosity of the adhesive/coating is low so that it self levels, and fills the cavity. Typical maximum depth of potting applications are <0.25 inches, but some special 2-part light-curable adhesives can be mixed to get a chemical reaction at deeper sections, while still allowing the benefit of a light-curable adhesive to lock in and seal the top surface. Moisture cure technology allows areas that can’t see UV/visible light to be cured with atmospheric moisture in the air, and takes a few hours to complete the cure.
What kinds of eye protection do you need when implementing UV-curable materials? DYMAX recommends that lights be fixtured to point away from the operators to avoid direct exposure. We provide tinted goggles that meet current ANSI standards, and some customers create custom shielding using brown PVC shielding or smoked/tinted polycarbonate sheet. We also provide training to operators as needed.
Will any of your adhesives continue to cure after the UV light has been removed? Some types of hybrid systems with moisture cure technology may continue to cure after the UV light has been removed. Some UV light-curable epoxies continue to harden slightly if they have achieved 90% of full cure, but extra care must be taken when working with these materials.
Are any of the light-curable materials RF & microwave frequency “friendly”? Yes. Certain formulations are compatible with RF and microwave frequencies, and are transparent to these wavelengths.
Is there any concern, other than cosmetic appearance, when yellowing of the cured media occurs? In other words, is there cure quality issues if yellowing occurs? Usually yellowing is a cosmetic phenomenon, with little impact on physical properties. Some optical applications do have a problem with yellowing as it would change the optical transmission of light through the adhesive. Therefore, an optically clear adhesive designed to be non-yellowing may be a good choice in this situation.
Can you overcure? Does the adhesive break-down? It is more difficult to overcure these acrylic-based light-cure adhesives. They are very forgiving, and it would have to be an extreme case of overcuring. However, I have seen a few cases where engineers put an adhesive under a static light source and went to lunch. Upon return, the adhesive had too much UV light at high intensity with too much resultant heat, and started to break down.
Do you recommend specific fillers that will not hinder the cure process? There are a number of fillers available on the market which do not hinder the cure process. Selecting the proper filler that yields a clear or translucent adhesive is a trick that the chemists use as they formulate.
Can you affect durometer with level of cure? If you plot durometer versus cure time with a constant intensity, you would actually see the durometer level off and plateau. Over-exposing the adhesive to 2x, 3x, 4x cure times do not usually have a negative effect.
What, if any, surface preparation is required to optimize the effectiveness of these adhesives? On some difficult to bond to substrates like PE and PP, surface preparation can improve the adhesion. Chemical primers, corona treatment, or plasma treatment (preferably with oxygen gas) are very commonly explored, as well as UV pretreatment of the surface.
How do you clean up “bleed out” or excess material? Removal of uncured adhesive after application can be done with a foam wipe, cloth, or cotton swab, followed with an alcohol wipe (isopropanol, methanol, or other organic solvent). We do have a technical bulletin available with suggestions on how to clean up both cured and uncured adhesive residue.
I have heard that pre-exposing the substrate to UV light has a similar effect to surface treatment. Can you comment on this? Pre-exposing a low-surface-energy plastic or substrate with high energy, short wavelength UV light is one effective way to increase adhesion, similar to other surface treatment options.
What is the pot life of adhesive once dispensed? As long as the adhesive is kept away from light and dust, it is okay for a long time. We generally recommend short work times since manufacturing environments typically have a little bit of visible light that could start to polymerize the material. Also dust contamination should be avoided.
Does the fluorescence of the adhesive change from pre-cure to post-cure? The fluorescence of the adhesive does not change from pre-cure to post-cure in most cases.
What packaging is available? We offer a number of different package sizes, from 3, 10, 30 mL syringes, 170, 300, 600 mL cartridges, L or kg bottles, 15 L pails, 55 gallon drums, and totes.
Add This! del.icio.us Digg Facebook reddit StumbleUpon

Adhesives, Curing Equipment , , , , , , , , ,